L5.5 Assembling the fine-structure corrections
PROFESSOR: So again, much of the difficulty here is just making sure you're doing the perturbation theory right and working with the two basis correctly. But now we're in the good position. We can combine our results. So here is what I want to combine. I want, in principle, to combine all the things, all the terms. And we've calculated all the terms to some degree. So we saw the Darwin term only affects l equals 0. On the other hand, spin orbit really requires s dot l. And the state should be acted nontrivially by l. If all your states are singlets, l gives 0 on them. So actually, you have a little bit of an uncomfortable situation because l acting on l equals 0 states will give you 0. But you still have the 1 over r cubed. And the 1 over r cubed has l dependencies here. So it's 0 in the denominator, 0 in the numerator. The whole spin orbit coupling doesn't seem to make sense for l equals 0. So most people say, physically, the spin orbit coupling vanis...