Student Video Tight Binding Model
STUDENT: Hello, everyone. Today, I'm going to talk about a very important model, analyze the energy band of a crystal, that is the tight binding model. Before I talk about tight binding model, let's now take a look at free electron model. The potential energy of free electron can be considered as zero, so the Hamiltonian of the free electron system is without the potential term. And the waveform function can be simply written as a plane wave. By substituting the wave function into Schrodinger equation, we can gather energy dispersion relation, which is a parabola in one dimension case. And we usually form the parabola into the first Brillouin zone. And this is the reduced Brillouin zone. And in this figure, we can see that the first band is at the bottom of the parabola. And the second band and third band, fourth, and so on. Similar to one dimension case, the energy of three dimension case is proportional to kx squared plus ky squared plus kz squared. For a given ...