16. Non-Degenerate Perturbation Theory II HO using a,a†
The following content is provided under a Creative Commons license. Your support will help MIT OpenCourseWare continue to offer high-quality educational resources for free. To make a donation or to view additional materials from hundreds of MIT courses, visit MIT OpenCourseWare at ocw.mit.edu. ROBERT FIELD: Today, I'm going to go over a lot of material that you already know and work an example with non-degenerate perturbation theory. This will give me an excuse to use interspersed matrix and operator notation, and one of the things that you will be doing is dealing with infinite matrices. And we don't diagonalize infinite matrices, but the picture of an infinite matrix is useful in guiding intuition. And so we have to know about what those pictures mean and how to construct them from things that seem to be obvious. OK, the problem I want to spend most of my time on is an example of a real molecular potential which is quadratic but with a cubic and a quartic pertur...